منابع مشابه
Transition Metal Free C–N Bond Forming Dearomatizations and Aryl C–H Aminations by in Situ Release of a Hydroxylamine-Based Aminating Agent
We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C-N bond forming dearomatization or aryl C-H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts activated N-Boc hydroxylamines.
متن کاملTotal synthesis of natural products using hypervalent iodine reagents
We present a review of natural product syntheses accomplished in our laboratory during the last 5 years. Each synthetic route features a phenol dearomatization promoted by an environmentally benign hypervalent iodine reagent. The dearomatizations demonstrate the "aromatic ring umpolung" concept, and involve stereoselective remodeling of the inert unsaturations of a phenol into a highly function...
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2019
ISSN: 1434-193X,1099-0690
DOI: 10.1002/ejoc.201901229